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• W1985481814 abstract "The kinetics of the electron transfer reactions of aquoiron(III) with ferrocene (Fer) and its n-butyl (BFer), 1,1′-dimethyl (DMFer) and 1,1′-di-n-butyl (DBFer) derivatives have been studied in the presence of cationic (CTAN) and non-ionic (Triton X-100) micelles at 20.0°C and ionic strength 0.02 mol dm−3. Both surfactants inhibit nearly at the same extent the reaction involving a given ferrocene derivative. The rate inhibition depends strongly on the alkyl groups present in the molecule of ferrocene, following the order DBFer > BFer > DMFer > Fer. The binding constants and the contribution of a methylene (or methyl) group of the alkyl substituents to the transfer free energy from water to micelle have been estimated and discussed, suggesting that ferrocenes are located inside the micelle." @default.
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• W1985481814 date "1985-01-01" @default.
• W1985481814 modified "2023-09-30" @default.
• W1985481814 title "Electron Transfer Reactions Between Iron (III) and Substituted Ferrocenes in Cationic and Non-Ionic Micellar Systems" @default.
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• W1985481814 doi "https://doi.org/10.1002/bbpc.19850890108" @default.
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