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- W1985498410 abstract "A simple and efficient method has been developed for remarkable rate acceleration and yield enhancement of the Baylis–Hillman reaction under solvent-free “neat conditions” and solvent-less isolation of products. Reaction of equimolar quantities of aldehyde and olefin in the presence of 20 mol% of DABCO under neat conditions affords the highest yield in most cases within the shortest reaction time, giving support to the mechanisms of proton transfer in protic and aprotic solvents. Solvent-free conditions are found to be especially fast, selective, and high yielding for aromatic aldehydes." @default.
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- W1985498410 date "2010-12-01" @default.
- W1985498410 modified "2023-09-30" @default.
- W1985498410 title "Baylis–Hillman reaction under solvent-free conditions — Remarkable rate acceleration and yield enhancement" @default.
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- W1985498410 doi "https://doi.org/10.1139/v10-133" @default.
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