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- W1985502608 abstract "Dynamics and mechanisms of infrared multiphoton dissociation of CBrF2CHClF, CBrF2CHBrF, and CBrClFCBrF2 have been studied using a photofragmentation translational spectroscopy. All molecules dissociated through C–Br bond rupture reactions. At high laser fluence, the halogenated ethyl radicals produced by the primary dissociation reactions dissociated through carbon–halogen bond ruptures. Center‐of‐mass product translational energy distributions for the C–Br and C–Cl bond ruptures of all halogenated ethanes and ethyl radicals studied are essentially consistent with those calculated by Rice–Ramsperger–Kassel–Marcus (RRKM) theory. This indicates that there exists essentially no exit channel barrier on the potential energy surface for the C–Br or C–Cl bond rupture of the halogenated ethanes and ethyl radicals." @default.
- W1985502608 created "2016-06-24" @default.
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- W1985502608 date "2010-08-18" @default.
- W1985502608 modified "2023-09-25" @default.
- W1985502608 title "ChemInform Abstract: Infrared Multiphoton Dissociation of CBrF2CHClF, CBrF2CHBrF, and CBrClFCBrF2 in a Molecular Beam" @default.
- W1985502608 cites W2952803866 @default.
- W1985502608 doi "https://doi.org/10.1002/chin.199521035" @default.
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