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- W1985514691 abstract "Cyanate esters and isostructural isocyanates have been synthesized and investigated in terms of their thermal and phase behaviour. Model cyclotrimers of both were synthesized to study the influence of the triazine rings on the mesophase formation. Liquid crystalline properties (calamitic mesophases) were found only for cyanurates. Polycyclotrimerization of 4-cyanatophenyl 4-cyanatobenzoate starts in an isotropic phase with a transition to a mesophase after reaching the gel point. The gel point observed by rheological measurements is temperature-dependent and probably caused by association of the reactive oligomers as no gel particles are found below the chemical gel point. The gel point of the commercial 2,2-bis(4-cyanatophenyl)propane was found at 50 % conversion by the same method. Due to the higher rigidity of the mesogenic cyanate the final conversion is below 100 %, as opposed to the conventional material. Under appropriate conditions isotropic networks can be obtained from the mesogenic monomer, which sets the basis for a quantitative investigation of the influence of liquid crystalline order on physical properties of the thermosets." @default.
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- W1985514691 date "1995-04-01" @default.
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- W1985514691 title "Anisotropic thermoset networks based on ring-forming monomers (cyanate esters and isocyanates)" @default.
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- W1985514691 doi "https://doi.org/10.1002/masy.19950930114" @default.
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