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• W1985523090 startingPage "998" @default.
• W1985523090 abstract "The C and O $1s$ photoelectron lines of the C${mathrm{O}}_{2}$ molecule in the gas phase have been measured with vibrational resolution in the threshold region. The vibrational fine structure on the O $1s$ line is completely dominated by the antisymmetric stretching mode with a frequency of 307 $(ifmmodepmelsetextpmfi{}3)mathrm{meV}$. This mode can be excited only via vibronic coupling, as predicted by Domcke and Cederbaum [Chem. Phys. 25, 189 (1977)], and provides a mechanism for dynamic core-hole localization. Relaxation effects are found to affect strongly the vibrational intensity distribution of the photoelectron line." @default.
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• W1985523090 date "1997-08-11" @default.
• W1985523090 modified "2023-09-23" @default.
• W1985523090 title "Vibrationally Resolved O<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mn>1</mml:mn><mml:mi mathvariant=italic>s</mml:mi></mml:math>Photoelectron Spectrum of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi>CO</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>: Vibronic Coupling and Dynamic Core-Hole Localization" @default.
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• W1985523090 doi "https://doi.org/10.1103/physrevlett.79.998" @default.
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