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- W1985535504 abstract "The cyclohexenylvinylidene complex fac,cis-[(PNP)RuCl2{CCH(CCHCH2CH2CH2CH2)}] (2) is synthesized by reaction of mer,trans-[(PNP)RuCl2(PPh3)] (1) with 1-ethynylcyclohexanol [PNPCH3CH2CH2N(CH2CH2PPh2)2]. Complex 2 reacts with water yielding fac,cis-[(PNP)RuCl2(CO)] and methylenecyclohexane. The regioselective incorporation of deuterium from D2O into the methylene group of methylenecyclohexane is consistent with the intermediacy of an η1-allyl ruthenium complex along the metal-assisted hydrolysis of the vinylidene CC bond. The hydrolysis of the alkenylvinylidenes fac,cis-[(PNP)RuCl2{CCHCRCH2}] (R=Me, Ph) proceeds similarly but the regioselectivity of deuterium incorporation depends on the temperature due to η1⇔η3 allyl interconversion." @default.
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- W1985535504 date "2000-01-01" @default.
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- W1985535504 title "Ruthenium-assisted synthesis of gem-deuterated alkenes from monosubstituted propargyl alcohols and D2O" @default.
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- W1985535504 doi "https://doi.org/10.1016/s0022-328x(99)00324-1" @default.
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