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• W1985536324 abstract "A review is given of the results obtained so far in the investigation of the optical rotatory dispersion or circular dichroism of a number of non-planar homoannular cisoid dienes. The findings agree in every instance with the predictions of a theoretical rule connecting the sign of the Cotton effect with the chirality of the diene; two seeming exceptions can be explained through detailed conformational analysis. The rule can therefore serve as a reliable basis for stereochemical studies on this class of dienes. As expected theoretically, the amplitudes of the Cotton effects produced by these inherently dissymmetric chromophores are very high, values up to 100,000 deg mol−1 having been found. However, steroidal 1,3-dienes form a separate group characterized by comparatively low amplitudes, in many instances associated with a distinctive shape of the curve." @default.
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• W1985536324 date "1965-01-01" @default.
• W1985536324 modified "2023-10-07" @default.
• W1985536324 title "Optical activity of non-planar conjugated dienes—I" @default.
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• W1985536324 doi "https://doi.org/10.1016/s0040-4020(01)96930-3" @default.
• W1985536324 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/5879262" @default.
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