FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1985557650> ?p ?o ?g. }

• W1985557650 endingPage "2259" @default.
• W1985557650 startingPage "2250" @default.
• W1985557650 abstract "The synthesis and properties of 3 new ligand-bridged bimetallic complexes, 1(2+), 2(2+), and 3(2+), containing [RuCl([9]aneS(3))](+) metal centers are reported. Each complex was bridged by a different ditopic ligand. 1(2+) is bridged by 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (bptz), while 2(2+) and 3(2+) are bridged by 2,3-bis(2-pyridyl)pyrazine (dpp) and 2,2'-bipyrimidine (bpym), respectively. The Ru([II]) isovalent states of these complexes have been investigated using a variety of techniques. In the case of 3(2+), X-ray crystallography studies show preferential crystallization of an anti form with respect to coordinated chloride ligands (crystal data for [3][Cl(2)].4H(2)O: C(20)H(38)Cl(4)N(4)O(4)Ru(2)S(6), monoclinic, space group P2(1)/a, a = 10.929(14), b = 13.514(17), c = 11.299(16) A, beta = 90.52(1), V = 1669 A(3), Z = 2). UV/vis spectroscopy shows that spectra of these complexes are dominated by intraligand (pi-->pi) and metal-to-ligand Ru(d)-->L(pi) charge transfer transitions. Electrochemical studies reveal that metal-metal interactions are sufficiently intense to generate the Ru(III)/Ru(II) mixed valence [[RuCl([9]aneS(3))(2)](L-L)](3+) state, where L-L = individual bridging ligands. Although the 1(3+), 2(3+), and 3(3+) mixed valence states were EPR silent at room temperature and 77 K, isotropic solution spectra were observed for the electrochemically generated radical cations 1(+), 2(+), and 3(+), with 1(+) displaying well-resolved hyperfine coupling to bridging ligand nitrogens. Using UV/vis/NIR spectroelectrochemistry, we investigated optical properties of the mixed valence complexes. All three showed intervalence charge transfer (IVCT) bands that are much more intense than electrochemical data indicate. Indeed, a comparison of IVCT data for 1(3+) with an analogous structure containing [(NH3)(3)Ru](2+) metal centers shows that the IVCT in the new complex is an order of magnitude more intense. It is concluded that although the new complexes show relatively weak electrostatic interactions, they possess large resonance energies." @default.
• W1985557650 created "2016-06-24" @default.
• W1985557650 creator A5006543336 @default.
• W1985557650 creator A5016994463 @default.
• W1985557650 creator A5026498456 @default.
• W1985557650 creator A5033413523 @default.
• W1985557650 creator A5043729606 @default.
• W1985557650 creator A5044285098 @default.
• W1985557650 creator A5065491764 @default.
• W1985557650 creator A5073660486 @default.
• W1985557650 creator A5074211409 @default.
• W1985557650 creator A5090416184 @default.
• W1985557650 date "2002-03-26" @default.
• W1985557650 modified "2023-10-13" @default.
• W1985557650 title "Ru^II Electron Transfer Systems Containing S-Donor Ligands" @default.
• W1985557650 cites W1691067281 @default.
• W1985557650 cites W1966846876 @default.
• W1985557650 cites W1968355139 @default.
• W1985557650 cites W1968983326 @default.
• W1985557650 cites W1974256758 @default.
• W1985557650 cites W1974744977 @default.
• W1985557650 cites W1987428834 @default.
• W1985557650 cites W1989010863 @default.
• W1985557650 cites W1996164437 @default.
• W1985557650 cites W1999139423 @default.
• W1985557650 cites W1999790690 @default.
• W1985557650 cites W2000831543 @default.
• W1985557650 cites W2000928387 @default.
• W1985557650 cites W2002802721 @default.
• W1985557650 cites W2006618691 @default.
• W1985557650 cites W2009108627 @default.
• W1985557650 cites W2009400031 @default.
• W1985557650 cites W2009749075 @default.
• W1985557650 cites W2012391712 @default.
• W1985557650 cites W2024382861 @default.
• W1985557650 cites W2026724426 @default.
• W1985557650 cites W2030175511 @default.
• W1985557650 cites W2034402791 @default.
• W1985557650 cites W2037081632 @default.
• W1985557650 cites W2038166085 @default.
• W1985557650 cites W2043763107 @default.
• W1985557650 cites W2044931258 @default.
• W1985557650 cites W2044988442 @default.
• W1985557650 cites W2046133238 @default.
• W1985557650 cites W2048383363 @default.
• W1985557650 cites W2050393976 @default.
• W1985557650 cites W2050463265 @default.
• W1985557650 cites W2056007138 @default.
• W1985557650 cites W2057815978 @default.
• W1985557650 cites W2064518468 @default.
• W1985557650 cites W2068700246 @default.
• W1985557650 cites W2069364101 @default.
• W1985557650 cites W2071259395 @default.
• W1985557650 cites W2073208473 @default.
• W1985557650 cites W2077749836 @default.
• W1985557650 cites W2084803362 @default.
• W1985557650 cites W2097329723 @default.
• W1985557650 cites W2101748147 @default.
• W1985557650 cites W2133494402 @default.
• W1985557650 cites W2141362681 @default.
• W1985557650 cites W2148066840 @default.
• W1985557650 cites W2159081899 @default.
• W1985557650 cites W2160737217 @default.
• W1985557650 cites W2161743998 @default.
• W1985557650 cites W2165268250 @default.
• W1985557650 cites W2329370268 @default.
• W1985557650 cites W2343799339 @default.
• W1985557650 cites W2497007159 @default.
• W1985557650 cites W2951168538 @default.
• W1985557650 cites W2951244738 @default.
• W1985557650 cites W2951895428 @default.
• W1985557650 cites W3004735026 @default.
• W1985557650 cites W3136968190 @default.
• W1985557650 cites W4248125359 @default.
• W1985557650 doi "https://doi.org/10.1021/ic010882i" @default.
• W1985557650 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11952382" @default.
• W1985557650 hasPublicationYear "2002" @default.
• W1985557650 type Work @default.
• W1985557650 sameAs 1985557650 @default.
• W1985557650 citedByCount "53" @default.
• W1985557650 countsByYear W19855576502012 @default.
• W1985557650 countsByYear W19855576502013 @default.
• W1985557650 countsByYear W19855576502014 @default.
• W1985557650 countsByYear W19855576502016 @default.
• W1985557650 countsByYear W19855576502017 @default.
• W1985557650 countsByYear W19855576502019 @default.
• W1985557650 countsByYear W19855576502020 @default.
• W1985557650 crossrefType "journal-article" @default.
• W1985557650 hasAuthorship W1985557650A5006543336 @default.
• W1985557650 hasAuthorship W1985557650A5016994463 @default.
• W1985557650 hasAuthorship W1985557650A5026498456 @default.
• W1985557650 hasAuthorship W1985557650A5033413523 @default.
• W1985557650 hasAuthorship W1985557650A5043729606 @default.
• W1985557650 hasAuthorship W1985557650A5044285098 @default.
• W1985557650 hasAuthorship W1985557650A5065491764 @default.
• W1985557650 hasAuthorship W1985557650A5073660486 @default.
• W1985557650 hasAuthorship W1985557650A5074211409 @default.
• W1985557650 hasAuthorship W1985557650A5090416184 @default.

• next