FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1985598537> ?p ?o ?g. }

• W1985598537 endingPage "5934" @default.
• W1985598537 startingPage "5923" @default.
• W1985598537 abstract "The synthesis and characterization of 6-hydroxymethylpyridine-2-carboxaldehyde (2-methyl-pyrimidine-4,6-diyl)bis(1-methylhydrazone) (1) is reported. Ligand 1 was designed as a ditopic pyrimidine-hydrazone molecular strand with hydroxymethyl groups attached to the terminal pyridine rings. Coordination of 1 with Cu(ClO(4))(2) x 6 H(2)O or Cu(SO(3)CF(3))(2) x 4 H(2)O in a 1:2 molar ratio resulted in the dinuclear Cu(II) complexes [Cu(2)1(CH(3)CN)(4)](ClO(4))(4) x CH(3)CN (4) and [Cu(2)1(SO(3)CF(3))(2)(CH(3)CN)(2)](SO(3)CF(3))(2) x CH(3)CN (5). X-ray crystallography and (1)H NMR NOESY experiments showed that 1 adopted a horseshoe shape with both pyrimidine-hydrazone (pym-hyz) bonds in a transoid conformation, while 4 and 5 were linear in shape, with both pym-hyz bonds in a cisoid conformation. Coordination of 1 with Cu(ClO(4))(2) x 6 H(2)O or Cu(SO(3)CF(3))(2) x 4 H(2)O in a 1:1 molar ratio resulted in three different bent complexes, [Cu(1H)(ClO(4))(2)](ClO(4)) (6), [Cu(1H)(CH(3)CN)](ClO(4))(3) x 0.5 H(2)O (7), and [Cu1(SO(3)CF(3))](2)(SO(3)CF(3))(2) x CH(3)CN (8), where the pym-hyz bond of the occupied coordination site adopted a cisoid conformation, while the pym-hyz bond of the unoccupied site retained a transoid conformation. Both 6 and 7 showed protonation of the pyridine nitrogen donor in the empty coordination site; complex 8, however, was not protonated. A variety of Cu(II) coordination geometries were seen in structures 4 to 8, including distorted octahedral, trigonal bipyramidal, and square pyramidal geometries. Coordination of the hydroxymethyl arm in the mononuclear Cu(II) complexes 6, 7, and 8 appeared to inhibit the formation of a [2 x 2] grid by blocking further access to the Cu(II) coordination sphere. In addition, the terminal hydroxymethyl groups contributed to the supramolecular structures of the complexes through coordination to the Cu(II) ions and hydrogen bonding." @default.
• W1985598537 created "2016-06-24" @default.
• W1985598537 creator A5040216713 @default.
• W1985598537 creator A5058960157 @default.
• W1985598537 creator A5076689125 @default.
• W1985598537 date "2010-05-28" @default.
• W1985598537 modified "2023-10-16" @default.
• W1985598537 title "Control of Self-Assembly through the Influence of Terminal Hydroxymethyl Groups on the Metal Coordination of Pyrimidine−Hydrazone Cu(II) Complexes" @default.
• W1985598537 cites W1765269712 @default.
• W1985598537 cites W1824436606 @default.
• W1985598537 cites W1964637375 @default.
• W1985598537 cites W1964685713 @default.
• W1985598537 cites W1965028337 @default.
• W1985598537 cites W1965407285 @default.
• W1985598537 cites W1966885039 @default.
• W1985598537 cites W1969609407 @default.
• W1985598537 cites W1969635440 @default.
• W1985598537 cites W1975015655 @default.
• W1985598537 cites W1982704944 @default.
• W1985598537 cites W1988095467 @default.
• W1985598537 cites W1994378543 @default.
• W1985598537 cites W1995293060 @default.
• W1985598537 cites W1999249530 @default.
• W1985598537 cites W2005517506 @default.
• W1985598537 cites W2009245264 @default.
• W1985598537 cites W2011274743 @default.
• W1985598537 cites W2012061330 @default.
• W1985598537 cites W2012979093 @default.
• W1985598537 cites W2017702218 @default.
• W1985598537 cites W2023941914 @default.
• W1985598537 cites W2029435949 @default.
• W1985598537 cites W2030827256 @default.
• W1985598537 cites W2054381338 @default.
• W1985598537 cites W2059108312 @default.
• W1985598537 cites W2063334178 @default.
• W1985598537 cites W2068426622 @default.
• W1985598537 cites W2074331742 @default.
• W1985598537 cites W2076458488 @default.
• W1985598537 cites W2079081383 @default.
• W1985598537 cites W2080444836 @default.
• W1985598537 cites W2082233082 @default.
• W1985598537 cites W2086945873 @default.
• W1985598537 cites W2089190844 @default.
• W1985598537 cites W2090648204 @default.
• W1985598537 cites W2091925397 @default.
• W1985598537 cites W2099497666 @default.
• W1985598537 cites W2105249240 @default.
• W1985598537 cites W2108975537 @default.
• W1985598537 cites W2122220082 @default.
• W1985598537 cites W2128869577 @default.
• W1985598537 cites W2148066840 @default.
• W1985598537 cites W2149292906 @default.
• W1985598537 cites W2158073836 @default.
• W1985598537 cites W2159081899 @default.
• W1985598537 cites W2164495714 @default.
• W1985598537 cites W2240258893 @default.
• W1985598537 cites W2395004775 @default.
• W1985598537 cites W2949764557 @default.
• W1985598537 doi "https://doi.org/10.1021/ic100384e" @default.
• W1985598537 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20509604" @default.
• W1985598537 hasPublicationYear "2010" @default.
• W1985598537 type Work @default.
• W1985598537 sameAs 1985598537 @default.
• W1985598537 citedByCount "26" @default.
• W1985598537 countsByYear W19855985372012 @default.
• W1985598537 countsByYear W19855985372013 @default.
• W1985598537 countsByYear W19855985372014 @default.
• W1985598537 countsByYear W19855985372015 @default.
• W1985598537 countsByYear W19855985372016 @default.
• W1985598537 countsByYear W19855985372017 @default.
• W1985598537 countsByYear W19855985372018 @default.
• W1985598537 countsByYear W19855985372019 @default.
• W1985598537 countsByYear W19855985372020 @default.
• W1985598537 countsByYear W19855985372021 @default.
• W1985598537 countsByYear W19855985372022 @default.
• W1985598537 crossrefType "journal-article" @default.
• W1985598537 hasAuthorship W1985598537A5040216713 @default.
• W1985598537 hasAuthorship W1985598537A5058960157 @default.
• W1985598537 hasAuthorship W1985598537A5076689125 @default.
• W1985598537 hasConcept C116569031 @default.
• W1985598537 hasConcept C155647269 @default.
• W1985598537 hasConcept C170493617 @default.
• W1985598537 hasConcept C178790620 @default.
• W1985598537 hasConcept C185592680 @default.
• W1985598537 hasConcept C2779321679 @default.
• W1985598537 hasConcept C2779485729 @default.
• W1985598537 hasConcept C2780349576 @default.
• W1985598537 hasConcept C2780591741 @default.
• W1985598537 hasConcept C544153396 @default.
• W1985598537 hasConcept C55493867 @default.
• W1985598537 hasConcept C68913812 @default.
• W1985598537 hasConcept C71240020 @default.
• W1985598537 hasConcept C8010536 @default.
• W1985598537 hasConceptScore W1985598537C116569031 @default.
• W1985598537 hasConceptScore W1985598537C155647269 @default.
• W1985598537 hasConceptScore W1985598537C170493617 @default.
• W1985598537 hasConceptScore W1985598537C178790620 @default.
• W1985598537 hasConceptScore W1985598537C185592680 @default.

• next