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- W1985604436 abstract "A novel micro/mesoporous composite material L-KIT-6 (LK) was successfully synthesized from zeolite L nano-crystals using low cost solid silica–alumina microsphere via two-step hydrothermal crystallization method. LK was used as catalyst support to prepare the hydrodesulfurization (HDS) catalyst. LK micro/mesoporous material and its corresponding catalyst CoMo/LK were characterized using XRD, FTIR, SEM, TEM, N2-adsorption, 27Al MAS NMR, Pyridine-FTIR, H2-TPR, XPS and HRTEM techniques. The physicochemical properties of CoMo/LK were compared with the reference catalysts with different support materials including zeolite L, KIT-6 and γ-Al2O3. The characterization results demonstrated that the textural and acidic properties of the LK composite were dramatically improved comparing with that of zeolite L and mesoporous silica KIT-6. Furthermore, LK had a positive effect on the formation of moderate MoS2 stacking morphology and more “edge” active centers. The catalyst CoMo/LK exhibited a superior catalytic performance for HDS of BT, which could be attributed to the synergistic effects of open porous structure, excellent textural property, appropriate acidity, and MoS2 stacking morphology of CoMo/LK. Moreover, a possible reaction network for BT HDS over CoMo/LK catalyst was proposed." @default.
- W1985604436 created "2016-06-24" @default.
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- W1985604436 date "2015-04-01" @default.
- W1985604436 modified "2023-10-09" @default.
- W1985604436 title "Synthesis of hierarchically porous L-KIT-6 silica–alumina material and the super catalytic performances for hydrodesulfurization of benzothiophene" @default.
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- W1985604436 doi "https://doi.org/10.1016/j.apcatb.2014.10.078" @default.
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