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- W1985607788 abstract "Fe+ has been coordinated to benzene and the extended aromatic coronene molecule in helium bath gas at 0.35±0.01 Torr and 295±2 K within a Selected-Ion Flow Tube (SIFT) tandem mass spectrometer. Rates were measured for reactions of the bare Fe+ ion, the C6H6Fe+ adduct and the C24H12Fe+ adduct with D2, N2, CO2, CH4, C2H2, C2H4, SO2, C6D6, NH3, H2O and CO. Comparisons of measured rates indicate that the presence of benzene and coronene leads to enhancements in the reactivity of bare Fe+ by up to five orders of magnitude. Ligation and sequential ligation was the only chemistry observed with most of the ligands investigated and the observed extent of ligation was employed to determine coordination numbers and these were rationalized in terms of the modes of coordination of Fe+ with the (flat) aromatic substrate and the ligand. However, bimolecular oxidation channels were observed to compete with ligation in the reactions with N2O and O2. The oxidation of Fe+ to form FeO+ with N2O was observed to be catalyzed by the presence of benzene or coronene. Fe-atom abstraction to form FeO2 was observed in the reactions with O2. The C6H6Fe+ adduct also eliminated water upon addition of O2 to form a benzometalcycle cation, FeC6H4O+, and was observed to be able to initiate the Fe+ catalyzed oxidation of benzene to 1,2-dihydroxybenzene (catechol)." @default.
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- W1985607788 date "2003-01-01" @default.
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- W1985607788 title "The gas-phase chemistry of iron cations coordinated to benzene and the extended aromatic coronene" @default.
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- W1985607788 doi "https://doi.org/10.1016/s1387-3806(02)00933-8" @default.
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