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- W1985634605 abstract "Abstract At room temperature, the reaction of metallic copper powder with 2-thenoyltrifluoroacetone (tfac) and selected phosphine ligands gives the new copper(I) complexes [Cu(PPh3)2(tfac)] (1), [Cu(dppm)–(tfac)]2 (2), [Cu(dppe)(tfac)]2 (3), [Cu(dppp)(tfac)] (4), [Cu(dppb)–(tfac)]2 (5), Ph2P(CH2)nPPh2 [n=1 (dppm), 2 (dppe), 3 (dppp), 4 (dppb)]. These complexes have been characterized by physicochemical and spectroscopic methods. X-ray structure analysis of 1 and 3 shows that tfac behaves as a chelating ligand and dppe coordinates as a bridging bidentate ligand to Cu(I) atoms in the Cu(I) complexes." @default.
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- W1985634605 date "2001-04-01" @default.
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- W1985634605 title "Synthesis of copper(I) β-diketone complexes" @default.
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- W1985634605 doi "https://doi.org/10.1016/s0277-5387(01)00715-x" @default.
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