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- W1985647552 abstract "The dehydration of fructose or glucose to 5-hydroxymethylfurfural (5-HMF) using room temperature ionic liquids (ILs) as a solvent is a promising method for producing liquid fuels from renewable resources. The IL, 1-hydroxyethyl-3-methylimidazolium tetrafluoroborate ([C2OHMIM]BF4), was used a catalyst—rather than as a solvent—in the conversion of fructose or glucose to 5-HMF. With glucose, the yield of 5-HMF reached as high as 67.3% after 1 h at 180 °C in dimethylsulfoxide (DMSO) as solvent. The catalyst was separated from the reaction mixture by distilling solvent and reused six times without loss of activity. Furthermore, a kinetic analysis was carried out to illustrate the formation of 5-HMF, and the values of the activation energy and the pre-exponential factor for the reaction were 55.77 kJ mol–1 and 1.6 × 104 min–1 respectively." @default.
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- W1985647552 date "2012-10-01" @default.
- W1985647552 modified "2023-10-18" @default.
- W1985647552 title "Efficient dehydration of glucose to 5-hydroxymethylfurfural catalyzed by the ionic liquid,1-hydroxyethyl-3-methylimidazolium tetrafluoroborate" @default.
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- W1985647552 doi "https://doi.org/10.1016/j.biortech.2012.06.081" @default.
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