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- W1985647908 abstract "The substitution reaction of bipyridyl with potassium trichloro (2,5-dimethyl 3-hexyne 2,5-diol) platinate(II) has been studied in 90% methanol -10 water mixtures at various temperatures. The reaction proceeds in several steps of which two have been well defined. Two rate constants were measured at 25°C: k1obs = 25 × 10−3 sec−1 k2obs = 0.2 × 10−3 sec−1 The first constant depends on the bipyridyl concentration and the second is independant of bipyridyl concentration. The rate constant found compared with those of Zeise's salt suggest a greater trans effect for the acetylenic glycol, as compared to the ethylene" @default.
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- W1985647908 date "1969-01-01" @default.
- W1985647908 modified "2023-09-30" @default.
- W1985647908 title "The kinetics of the reaction of bipyridyl with potassium trichloro (2,5-dimethyl 3-hexyne 2,5-diol)platinate(II)" @default.
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- W1985647908 doi "https://doi.org/10.1016/s0020-1693(00)92518-0" @default.
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