Matches in SemOpenAlex for { <https://semopenalex.org/work/W1985657652> ?p ?o ?g. }
- W1985657652 endingPage "11530" @default.
- W1985657652 startingPage "11519" @default.
- W1985657652 abstract "Several new bis-phosphine platinum(II) complexes with 2,5-diaryl-substituted oxazole-containing alkyne ligands have been synthesized and optically characterized in solution. Measurements of nonlinear absorption showed strong attenuation of laser light at 532 and 600 nm. The light absorption of the Pt complexes was shifted from the near-UV region for the ground state to the red region for the excited triplet state, and was associated with large extinction coefficients. The optical limiting effect can be explained by triplet–triplet excited state absorption in conjunction with fast excited singlet–to-triplet intersystem crossing and slow triplet–to-ground-state decay, in comparison with the pulse length of the laser. DFT calculations show good predictability of the S0–S1 and S0–T1 energy gaps and offer insight into the interaction strength between Pt and the alkyne ligands. The use of this type of ligand, with weak absorption for the Pt(II) complexes in the visual wavelength range as a key feature, enables the possibility to further improve these molecular systems for nonlinear absorption applications." @default.
- W1985657652 created "2016-06-24" @default.
- W1985657652 creator A5001759195 @default.
- W1985657652 creator A5035915915 @default.
- W1985657652 creator A5037705010 @default.
- W1985657652 creator A5041121330 @default.
- W1985657652 creator A5052435087 @default.
- W1985657652 creator A5069618805 @default.
- W1985657652 date "2012-11-13" @default.
- W1985657652 modified "2023-10-16" @default.
- W1985657652 title "Photophysical and DFT Characterization of Novel Pt(II)-Coupled 2,5-Diaryloxazoles for Nonlinear Optical Absorption" @default.
- W1985657652 cites W1505603969 @default.
- W1985657652 cites W1922430275 @default.
- W1985657652 cites W1972375509 @default.
- W1985657652 cites W1973296730 @default.
- W1985657652 cites W1977758654 @default.
- W1985657652 cites W1981207526 @default.
- W1985657652 cites W1981317388 @default.
- W1985657652 cites W1989854295 @default.
- W1985657652 cites W1994401491 @default.
- W1985657652 cites W1998925476 @default.
- W1985657652 cites W2002966615 @default.
- W1985657652 cites W2003269140 @default.
- W1985657652 cites W2005854240 @default.
- W1985657652 cites W2007331943 @default.
- W1985657652 cites W2009709957 @default.
- W1985657652 cites W2015723183 @default.
- W1985657652 cites W2017295395 @default.
- W1985657652 cites W2020586725 @default.
- W1985657652 cites W2023271753 @default.
- W1985657652 cites W2024059784 @default.
- W1985657652 cites W2024285697 @default.
- W1985657652 cites W2024727005 @default.
- W1985657652 cites W2025855478 @default.
- W1985657652 cites W2029923711 @default.
- W1985657652 cites W2032429324 @default.
- W1985657652 cites W2033148887 @default.
- W1985657652 cites W2034010127 @default.
- W1985657652 cites W2034450153 @default.
- W1985657652 cites W2043773679 @default.
- W1985657652 cites W2050226884 @default.
- W1985657652 cites W2051041854 @default.
- W1985657652 cites W2056185213 @default.
- W1985657652 cites W2056793197 @default.
- W1985657652 cites W2057011153 @default.
- W1985657652 cites W2060260152 @default.
- W1985657652 cites W2062852634 @default.
- W1985657652 cites W2064226199 @default.
- W1985657652 cites W2069173454 @default.
- W1985657652 cites W2070157536 @default.
- W1985657652 cites W2071401289 @default.
- W1985657652 cites W2072552784 @default.
- W1985657652 cites W2074915413 @default.
- W1985657652 cites W2078833407 @default.
- W1985657652 cites W2081642767 @default.
- W1985657652 cites W2086957099 @default.
- W1985657652 cites W2092391617 @default.
- W1985657652 cites W2093535649 @default.
- W1985657652 cites W2104099569 @default.
- W1985657652 cites W2107626891 @default.
- W1985657652 cites W2114239021 @default.
- W1985657652 cites W2143981217 @default.
- W1985657652 cites W2152248364 @default.
- W1985657652 cites W2155990440 @default.
- W1985657652 cites W2160790360 @default.
- W1985657652 cites W2322770515 @default.
- W1985657652 cites W2493041787 @default.
- W1985657652 cites W3005195844 @default.
- W1985657652 doi "https://doi.org/10.1021/jp307312v" @default.
- W1985657652 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23102256" @default.
- W1985657652 hasPublicationYear "2012" @default.
- W1985657652 type Work @default.
- W1985657652 sameAs 1985657652 @default.
- W1985657652 citedByCount "16" @default.
- W1985657652 countsByYear W19856576522013 @default.
- W1985657652 countsByYear W19856576522014 @default.
- W1985657652 countsByYear W19856576522015 @default.
- W1985657652 countsByYear W19856576522018 @default.
- W1985657652 countsByYear W19856576522019 @default.
- W1985657652 countsByYear W19856576522020 @default.
- W1985657652 countsByYear W19856576522022 @default.
- W1985657652 crossrefType "journal-article" @default.
- W1985657652 hasAuthorship W1985657652A5001759195 @default.
- W1985657652 hasAuthorship W1985657652A5035915915 @default.
- W1985657652 hasAuthorship W1985657652A5037705010 @default.
- W1985657652 hasAuthorship W1985657652A5041121330 @default.
- W1985657652 hasAuthorship W1985657652A5052435087 @default.
- W1985657652 hasAuthorship W1985657652A5069618805 @default.
- W1985657652 hasConcept C119824511 @default.
- W1985657652 hasConcept C120665830 @default.
- W1985657652 hasConcept C121332964 @default.
- W1985657652 hasConcept C125287762 @default.
- W1985657652 hasConcept C178790620 @default.
- W1985657652 hasConcept C181500209 @default.
- W1985657652 hasConcept C184779094 @default.
- W1985657652 hasConcept C185592680 @default.
- W1985657652 hasConcept C32909587 @default.
- W1985657652 hasConcept C33062035 @default.