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- W1985661602 abstract "The substance 2,6-di-tert-butylphenol acts as a strong retarder for the cationic polymerization of isobutene. Spectroscopic studies show that the growing polymer cation attacks the phenol at the basic 4-position. Analysis of the kinetic and degree of polymerization results yields estimates of the rates of initiation of the polymerization.The initiation reaction in the polymerization of isobutene in ethyl chloride at −78.5°C with stannic chloride and a coinitiator appears to be a first-order process. Rate constants for the initiation reaction include 4 × 10−6sec−1 for water as coinitiator, 3.8 × 10−5sec−1 for 2,6-dimethylphenol, 7.5 × 10−5sec−1 for 2,4,6-trimethylphenol, 3.1 × 10−5sec−1 for 2,3,5,6-tetramethylphenol, 7 × 10−5 sec−1 for 2,3,4,6-tetramethylphenol, and 1.5 × 10−3sec−1 for acetic acid." @default.
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- W1985661602 date "2007-03-08" @default.
- W1985661602 modified "2023-09-23" @default.
- W1985661602 title "Rates of initiation of the cationic polymerization of isobutene" @default.
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- W1985661602 doi "https://doi.org/10.1002/polc.5070560119" @default.
- W1985661602 hasPublicationYear "2007" @default.
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