Matches in SemOpenAlex for { <https://semopenalex.org/work/W1985666552> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W1985666552 endingPage "2379" @default.
- W1985666552 startingPage "2375" @default.
- W1985666552 abstract "The reaction of anthracene with benzoyl peroxide (BPO) in benzene solution gives 9-benzoyloxyanthracene (I), without forming any 9,10-dibenzoyloxyanthracene (II). However, in the presence of sulfur dioxide (SO2), the above mentioned reaction produces II, 9,9′-dianthrone (III), and anthraquinone (IV), without any I. These reaction mechanisms could be interpreted as follows: It is considered that, in the addition reaction of anthracene with a benzoyloxy radical (PhCOO·), the 9,10-dihydro-9-benzoyloxyanthryl radical (V) is formed. In the absence of SO2, an intra-molecular aromatization of V occurs by a hydrogen abstraction and a delocalization of the radical. On the contrary, in the presence of SO2, the localization of the V radical is enhanced by the interaction with SO2, thus promoting the reactivity toward the benzoyloxy radical. Moreover, in the experiments using α, α′-azobis-isobutyronitrile (AIBN) in place of BPO, the addition products of 2-cyano-2-propyl radicals with anthracene were isolated. This phenomenon could be explained by the fact that the hydrogen abstractions of the addition products do not occur." @default.
- W1985666552 created "2016-06-24" @default.
- W1985666552 creator A5051428004 @default.
- W1985666552 creator A5061985172 @default.
- W1985666552 creator A5068383091 @default.
- W1985666552 date "1967-10-01" @default.
- W1985666552 modified "2023-09-23" @default.
- W1985666552 title "The Effect of Sulfur Dioxide in the Radical Reactions of Anthracene" @default.
- W1985666552 cites W1556023044 @default.
- W1985666552 cites W1963688013 @default.
- W1985666552 cites W2091501599 @default.
- W1985666552 cites W2112282358 @default.
- W1985666552 cites W2312670170 @default.
- W1985666552 cites W2314392508 @default.
- W1985666552 cites W2314855399 @default.
- W1985666552 cites W2315247356 @default.
- W1985666552 cites W2317940084 @default.
- W1985666552 cites W2321026547 @default.
- W1985666552 cites W2326053928 @default.
- W1985666552 cites W2328176384 @default.
- W1985666552 cites W2330898407 @default.
- W1985666552 cites W2331367286 @default.
- W1985666552 cites W2331902312 @default.
- W1985666552 cites W2937650984 @default.
- W1985666552 cites W84391694 @default.
- W1985666552 doi "https://doi.org/10.1246/bcsj.40.2375" @default.
- W1985666552 hasPublicationYear "1967" @default.
- W1985666552 type Work @default.
- W1985666552 sameAs 1985666552 @default.
- W1985666552 citedByCount "3" @default.
- W1985666552 countsByYear W19856665522015 @default.
- W1985666552 crossrefType "journal-article" @default.
- W1985666552 hasAuthorship W1985666552A5051428004 @default.
- W1985666552 hasAuthorship W1985666552A5061985172 @default.
- W1985666552 hasAuthorship W1985666552A5068383091 @default.
- W1985666552 hasBestOaLocation W19856665521 @default.
- W1985666552 hasConcept C139066938 @default.
- W1985666552 hasConcept C142724271 @default.
- W1985666552 hasConcept C155647269 @default.
- W1985666552 hasConcept C161790260 @default.
- W1985666552 hasConcept C169749651 @default.
- W1985666552 hasConcept C178790620 @default.
- W1985666552 hasConcept C185592680 @default.
- W1985666552 hasConcept C204787440 @default.
- W1985666552 hasConcept C2776910235 @default.
- W1985666552 hasConcept C2777691172 @default.
- W1985666552 hasConcept C2778913731 @default.
- W1985666552 hasConcept C2779325354 @default.
- W1985666552 hasConcept C2779563022 @default.
- W1985666552 hasConcept C2780447027 @default.
- W1985666552 hasConcept C2780995637 @default.
- W1985666552 hasConcept C44228677 @default.
- W1985666552 hasConcept C521977710 @default.
- W1985666552 hasConcept C71924100 @default.
- W1985666552 hasConcept C75473681 @default.
- W1985666552 hasConcept C81022585 @default.
- W1985666552 hasConceptScore W1985666552C139066938 @default.
- W1985666552 hasConceptScore W1985666552C142724271 @default.
- W1985666552 hasConceptScore W1985666552C155647269 @default.
- W1985666552 hasConceptScore W1985666552C161790260 @default.
- W1985666552 hasConceptScore W1985666552C169749651 @default.
- W1985666552 hasConceptScore W1985666552C178790620 @default.
- W1985666552 hasConceptScore W1985666552C185592680 @default.
- W1985666552 hasConceptScore W1985666552C204787440 @default.
- W1985666552 hasConceptScore W1985666552C2776910235 @default.
- W1985666552 hasConceptScore W1985666552C2777691172 @default.
- W1985666552 hasConceptScore W1985666552C2778913731 @default.
- W1985666552 hasConceptScore W1985666552C2779325354 @default.
- W1985666552 hasConceptScore W1985666552C2779563022 @default.
- W1985666552 hasConceptScore W1985666552C2780447027 @default.
- W1985666552 hasConceptScore W1985666552C2780995637 @default.
- W1985666552 hasConceptScore W1985666552C44228677 @default.
- W1985666552 hasConceptScore W1985666552C521977710 @default.
- W1985666552 hasConceptScore W1985666552C71924100 @default.
- W1985666552 hasConceptScore W1985666552C75473681 @default.
- W1985666552 hasConceptScore W1985666552C81022585 @default.
- W1985666552 hasIssue "10" @default.
- W1985666552 hasLocation W19856665521 @default.
- W1985666552 hasOpenAccess W1985666552 @default.
- W1985666552 hasPrimaryLocation W19856665521 @default.
- W1985666552 hasRelatedWork W1985666552 @default.
- W1985666552 hasRelatedWork W2006848508 @default.
- W1985666552 hasRelatedWork W2010669409 @default.
- W1985666552 hasRelatedWork W2031208521 @default.
- W1985666552 hasRelatedWork W2081876296 @default.
- W1985666552 hasRelatedWork W2088677220 @default.
- W1985666552 hasRelatedWork W2106546487 @default.
- W1985666552 hasRelatedWork W2177657295 @default.
- W1985666552 hasRelatedWork W2496332627 @default.
- W1985666552 hasRelatedWork W2949546878 @default.
- W1985666552 hasVolume "40" @default.
- W1985666552 isParatext "false" @default.
- W1985666552 isRetracted "false" @default.
- W1985666552 magId "1985666552" @default.
- W1985666552 workType "article" @default.