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• W1985673816 startingPage "5732" @default.
• W1985673816 abstract "We describe a prototype designed for in situ detection of the nitrate radical (NO3) by laser-induced fluorescence (LIF) and of N2O5 by thermal dissociation followed by LIF detection of NO3. An inexpensive 36 mW continuous wave multi-mode diode laser at 662 nm is used to excite NO3 in the B2E'(0000) <-- X2A'2(0000) band. Fluorescence is collected from 700 to 750 nm. The prototype has a sensitivity to NO3 of 76 ppt for a 60 s integration with an accuracy of 8%. Although this sensitivity is adequate for studies of N205 in many environments, it is much less sensitive (about 300 times) than expected based on a comparison of previously measured photophysical properties of NO2 and NO3. This implies much stronger nonradiative coupling of electronic states in NO3 than in NO2." @default.
• W1985673816 created "2016-06-24" @default.
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• W1985673816 date "2003-11-04" @default.
• W1985673816 modified "2023-10-10" @default.
• W1985673816 title "Prototype for In Situ Detection of Atmospheric NO₃ and N₂O₅ via Laser-Induced Fluorescence" @default.
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• W1985673816 doi "https://doi.org/10.1021/es034507w" @default.
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• W1985673816 hasPublicationYear "2003" @default.
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