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- W1985693325 abstract "A capillary electrophoresis method with contactless conductivity detection was developed for the quantification of carnitine and six acylcarnitines in plasma and urine samples. The running buffer employed consisted of 500 mmol/L acetic acid, 1.0 mmol/L hydroxypropyl-β-cyclodextrin and 0.05% Tween at a pH of 2.6. Under these conditions, the isomeric valproyl- and octanoyl-carnitines could be distinguished. The linearity was in the range from 5.0 to 200.0 μmol/L with correlation coefficients between 0.9992 and 0.9997. The limits of detection were between 1.0 and 3.2 μmol/L. Intra- and inter-day precisions as %RSD were better than 10%. The method allows for direct determination without derivatisation or extraction processes. The method was applied for the quantification of carnitine and acetylcarnitine in plasma pre- and post-exercise, and to measure valproylcarnitine in plasma and urine of patients undergoing valproate therapy." @default.
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- W1985693325 date "2011-04-01" @default.
- W1985693325 modified "2023-10-07" @default.
- W1985693325 title "Capillary electrophoresis with contactless conductivity detection for the determination of carnitine and acylcarnitines in clinical samples" @default.
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- W1985693325 doi "https://doi.org/10.1016/j.jchromb.2011.02.046" @default.
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