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- W1985694402 abstract "Abstract PtBr 2 / n Bu 4 PBr (without solvent) or K 2 PtCl 4 /NaBr (in water) have been shown to efficiently catalyze the hydroamination of ethylene by aniline and are poor catalysts for the hydroamination of ethylene by diethylamine. A DFT study on the hydroamination mechanism indicates that the energetic span of the C 2 H 4 /Et 2 NH catalytic cycle is close to that of the C 2 H 4 /PhNH 2 cycle. The poor performance is attributed to rapid catalyst degradation with reduction to metallic platinum. Pt 0 , on the other hand, catalyzes a transalkylation process, partially transforming Et 2 NH into Et 3 N, EtNH 2 and NH 3 . This process is inhibited by C 2 H 4 . Mechanistic considerations for the Pt 0 ‐catalyzed transalkylation process are presented." @default.
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- W1985694402 date "2011-10-21" @default.
- W1985694402 modified "2023-10-09" @default.
- W1985694402 title "Reactions of Diethylamine and Ethylene Catalyzed by Pt<sup>II</sup> or Pt<sup>0</sup> – Transalkylation vs. Hydroamination" @default.
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- W1985694402 doi "https://doi.org/10.1002/ejic.201100624" @default.
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