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- W1985698002 abstract "The isomeric trimethylsilyl substituted cyclohexenes, 1-trimethylsilylcyclohexene, 3-trimethylsilylcyclohexene, and 4-trimethylsilylcyclohexene and the analogous trimethylsilyl substituted cyclopentenes, 1-trimethylsilylcyclopentene, 3-trimethylsilylcyclopentene and 4-trimethylsilylcyclopentene have been hydroborated and oxidized under kinetic and thermodynamic conditions. The hydroborating agents used were borane and thexylborane in THF. The products of these reactions show a dependence on temperature and the hydroborating agent used and are a result of a rather facile migration of the boron atom around the ring. Some synthetically useful reactions are discussed as are the structures of various trimethylsilyl substituted cyclohexanols and cyclopentanols." @default.
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- W1985698002 date "1977-05-01" @default.
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- W1985698002 title "The hydroboration-oxidation of the isomeric trimethylsilylcyclo- hexenes and the isomeric trimethylsilylcyclopentenes." @default.
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- W1985698002 doi "https://doi.org/10.1016/s0022-328x(00)91736-4" @default.
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