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- W1985703529 abstract "The complexes [PdLCl2]1, [PtLCl2]2, [PtL(SnCl3)Cl]3 and [RhL(CO)Cl]4, where L is the chiral pyridylphosphine 4-(diphenylphosphinomethyl)-2,2-dimethyl-5-(2-pyridyl)-1,3-dioxolane, have been synthesized and characterized by IR, NMR and FAB mass spectra. The structure of compound 1 has been solved by X-ray diffraction: the ligand is co-ordinated through both the P and N atoms to form a seven-membered ring which adopts a chair conformation. One of the hydrogen atoms of the backbone is located 2.72(3)Å over the palladium atom in a pseudo-axial position. Spectroscopic evidence supports a chelating behaviour of the ligand also in compounds 2 and 3. The behaviour of the L ligand in the rhodium(I) species 4 is discussed." @default.
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- W1985703529 date "1996-01-01" @default.
- W1985703529 modified "2023-10-17" @default.
- W1985703529 title "Synthesis and characterization of square-planar palladium(II), platinum(II) and rhodium(I) complexes with a chiral pyridylphosphine hybrid ligand" @default.
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- W1985703529 doi "https://doi.org/10.1039/dt9960001295" @default.
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