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- W1985706070 abstract "A new noncovalent approach for the dissolution and exfoliation of SWNTs in water by a rigid, planar and conjugated diazo dye, Congo red (CR), is reported. Using a simple physical grinding treatment, the mixture of SWNTs and CR can be dissolved in water with a solubility as high as 3.5 mg/ml for SWNTs. The complete elimination of free CR from the mixture hardly changed this excellent solubility. High-resolution transmission electron microscope images showed that the SWNTs bundles were efficiently exfoliated into individual SWNTs or small ropes, which was further demonstrated by the increased π-plasmon UV–vis absorption and the upshift of the radical breathing mode in Raman scatterings. The π-stacking interaction between adsorbed CR and SWNTs was considered responsible for the high solubility. The uninterrupted structure of SWNTs with CR functionalization was ascertained by the unchanged disorder-induced Raman scattering." @default.
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- W1985706070 date "2006-03-01" @default.
- W1985706070 modified "2023-10-13" @default.
- W1985706070 title "Water-soluble single-walled carbon nanotubes via noncovalent functionalization by a rigid, planar and conjugated diazo dye" @default.
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- W1985706070 doi "https://doi.org/10.1016/j.carbon.2005.09.003" @default.
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