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• W1985709368 endingPage "314" @default.
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• W1985709368 abstract "A comprehensive XPS/XAES investigation of the dense 6:3 co-ordinated SiO2 polymorph stishovite in comparison with different SiO4/2 samples and Si was carried out for the first time. By evaluation of initial state and final state shift contributions, effective charges and extra-atomic relaxation energies were determined and discussed in the context of the electronic structure for different co-ordination numbers. The reduced binding energies of Si and O lines for stishovite are due to the higher extra-atomic relaxation energy in comparison to SiO4/2, which correlates with the higher dielectric constant and the lower gap energy in SiO6/3. The effective charges are only slightly higher in stishovite than e.g. in quartz." @default.
• W1985709368 created "2016-06-24" @default.
• W1985709368 creator A5048588657 @default.
• W1985709368 date "1988-07-01" @default.
• W1985709368 modified "2023-09-25" @default.
• W1985709368 title "SiO2 in 6:3 (stishovite) and 4:2 Co-ordination—Characterization by core level spectroscopy (XPS/XAES)" @default.
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• W1985709368 doi "https://doi.org/10.1002/sia.740120507" @default.
• W1985709368 hasPublicationYear "1988" @default.
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