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• W1985727049 endingPage "56" @default.
• W1985727049 startingPage "31" @default.
• W1985727049 abstract "This paper represents a call to the broader XAS community to more closely assess dose, as well as the other experimental factors (detection method, temperature, pressure and sample conditions) that affect the rate of X-ray induced chemistry during metal L-edge (as well as other) XAS measurements. While there have been detailed studies on photoreduction within the X-ray community, which have aimed to establish dose–photoreduction relations, it is our view that further standardization of data collection and reporting procedures are required. For molecules as simple as KMnO4 and K3[Fe(CN)6], the literature reported Mn and Fe L-edges, respectively, vary greatly in both overall shapes and spectral distributions. In addition, the reported experimental procedures are often not sufficient to establish the dose–photoreduction relationships. In an effort to more rigorously and quantitatively address this issue, we have measured Mn and Fe L-edge data on KMnO4 and K3[Fe(CN)6] at seven beam lines around the world. We demonstrate that while at a given beam line under identical experimental conditions, there is a dose–photoreduction correlation, this correlation does not hold across different experimental setups or upon variation of the experimental conditions at the same beam line. We introduce a Matlab-script XASskindose to calculate the absorbed dose related to a spectrum. By quantifying the rate of reduction (k), half-dose (D1/2) and the, here introduced, spectroscopically tolerable dose (Dst) values, we find that these values can vary by up to two orders of magnitude for the same compound. Hence, the results presented herein, indicate that a simple dose–photoreduction correlation is insufficient for predicting the rate of X-ray induced changes within a sample. The need to also consider detection method, temperature, pressure and sample conditions are discussed, and correlated to experimental data. A generalized reporting procedure for the broader XAS community is proposed in order to streamline the assessment of reported spectra. In addition, G-values are proposed as a means to predict the rate of metal ion photoreduction prior to an XAS measurement at any beamline by considering the metal ion type, its oxidation state and its stoichiometry in a compound, together with the dose ratio of the compound." @default.
• W1985727049 created "2016-06-24" @default.
• W1985727049 creator A5053491539 @default.
• W1985727049 creator A5070632432 @default.
• W1985727049 date "2015-01-01" @default.
• W1985727049 modified "2023-09-29" @default.
• W1985727049 title "A close look at dose: Toward L-edge XAS spectral uniformity, dose quantification and prediction of metal ion photoreduction" @default.
• W1985727049 cites W1603328944 @default.
• W1985727049 cites W1964231011 @default.
• W1985727049 cites W1964958276 @default.
• W1985727049 cites W1969464963 @default.
• W1985727049 cites W1973128310 @default.
• W1985727049 cites W1973348015 @default.
• W1985727049 cites W1973893718 @default.
• W1985727049 cites W1976618506 @default.
• W1985727049 cites W1977061694 @default.
• W1985727049 cites W1978644901 @default.
• W1985727049 cites W1979250660 @default.
• W1985727049 cites W1979291186 @default.
• W1985727049 cites W1983573567 @default.
• W1985727049 cites W1986204515 @default.
• W1985727049 cites W1988521079 @default.
• W1985727049 cites W1989060017 @default.
• W1985727049 cites W1990278156 @default.
• W1985727049 cites W1991736821 @default.
• W1985727049 cites W1993638870 @default.
• W1985727049 cites W1993697064 @default.
• W1985727049 cites W1995540886 @default.
• W1985727049 cites W1997110221 @default.
• W1985727049 cites W1999731009 @default.
• W1985727049 cites W2000877740 @default.
• W1985727049 cites W2006593078 @default.
• W1985727049 cites W2007268815 @default.
• W1985727049 cites W2009666354 @default.
• W1985727049 cites W2009678088 @default.
• W1985727049 cites W2010735747 @default.
• W1985727049 cites W2012456514 @default.
• W1985727049 cites W2013871928 @default.
• W1985727049 cites W2020241645 @default.
• W1985727049 cites W2022979093 @default.
• W1985727049 cites W2023910207 @default.
• W1985727049 cites W2024736890 @default.
• W1985727049 cites W2025627981 @default.
• W1985727049 cites W2025788340 @default.
• W1985727049 cites W2027245741 @default.
• W1985727049 cites W2027745601 @default.
• W1985727049 cites W2028520880 @default.
• W1985727049 cites W2029690585 @default.
• W1985727049 cites W2030315684 @default.
• W1985727049 cites W2033285121 @default.
• W1985727049 cites W2033600045 @default.
• W1985727049 cites W2034345897 @default.
• W1985727049 cites W2034979775 @default.
• W1985727049 cites W2035256500 @default.
• W1985727049 cites W2035833418 @default.
• W1985727049 cites W2041494763 @default.
• W1985727049 cites W2045643278 @default.
• W1985727049 cites W2046049130 @default.
• W1985727049 cites W2046254825 @default.
• W1985727049 cites W2048999806 @default.
• W1985727049 cites W2051054871 @default.
• W1985727049 cites W2052721424 @default.
• W1985727049 cites W2052971931 @default.
• W1985727049 cites W2053411028 @default.
• W1985727049 cites W2057998718 @default.
• W1985727049 cites W2058250321 @default.
• W1985727049 cites W2058994515 @default.
• W1985727049 cites W2059216682 @default.
• W1985727049 cites W2061500193 @default.
• W1985727049 cites W2064010176 @default.
• W1985727049 cites W2065403922 @default.
• W1985727049 cites W2068434639 @default.
• W1985727049 cites W2069987331 @default.
• W1985727049 cites W2075421001 @default.
• W1985727049 cites W2076161510 @default.
• W1985727049 cites W2076549313 @default.
• W1985727049 cites W2076668906 @default.
• W1985727049 cites W2077959586 @default.
• W1985727049 cites W2081751106 @default.
• W1985727049 cites W2082062361 @default.
• W1985727049 cites W2084953647 @default.
• W1985727049 cites W2086470686 @default.
• W1985727049 cites W2087323383 @default.
• W1985727049 cites W2087599743 @default.
• W1985727049 cites W2087758589 @default.
• W1985727049 cites W2087929108 @default.
• W1985727049 cites W2089511067 @default.
• W1985727049 cites W2092569579 @default.
• W1985727049 cites W2092746692 @default.
• W1985727049 cites W2092954746 @default.
• W1985727049 cites W2093162739 @default.
• W1985727049 cites W2095961552 @default.
• W1985727049 cites W2096835808 @default.
• W1985727049 cites W2098557226 @default.
• W1985727049 cites W2100800138 @default.
• W1985727049 cites W2101804432 @default.
• W1985727049 cites W2103214864 @default.
• W1985727049 cites W2109695616 @default.

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