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- W1985727716 abstract "Some theories for the anomalous conduction phenomenon of the mixed alkali glasses predict or rely on a particular type of glass structure; either a clustering tendency with positive enthalpy of mixing or an ordering tendency with negative enthalpy of mixing between two dissimilar alkali species. For example, according to a theory based upon the thermodynamic state of glasses suggested by the present author and his collaborator, the large static dielectric relaxation strength and corresponding low dc conductivity observed for mixed alkali glasses indicate a negative enthalpy of mixing. Independent experiments, however, have shown both positive enthalpy of mixing and negative enthalpy of mixing, Mixed alkali glasses have larger static dielectric constant but smaller high frequency dielectric constant than the corresponding single alkali glasses. This difference indicates that the mixed alkali glasses have a negative enthalpy of mixing under dc electric fields but a positive enthalpy of mixing under high frequency electric field. It is suggested that the structural studies made under dc electric field or involving ion-exchange are relevant to the mixed alkali effect." @default.
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- W1985727716 date "1996-03-01" @default.
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- W1985727716 title "Structure of mixed alkali glasses" @default.
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- W1985727716 doi "https://doi.org/10.1016/0022-3093(95)00600-1" @default.
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