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• W1985732970 abstract "Asymmetric epoxidation of unfunctionalized alkenes is reported using chiral (salen)Mn(III) complexes 1–5 together with a carboxylate salt cocatalyst in the presence of either aqueous H2O2 or anhydrous urea-H2O2 adduct as oxidant. Several simple soluble salts (acetates, formates, benzoates) were studied all giving good yields of epoxides with moderate to excellent enantioselectivity. For example, 1,1-diphenyl-1-propene was converted into the corresponding epoxide of 96 % ee in 84 % yield. Generally, this epoxidation method gave better results than a previously described system using nitrogen heterocycles as cocatalysts." @default.
• W1985732970 created "2016-06-24" @default.
• W1985732970 creator A5082623113 @default.
• W1985732970 date "1998-04-01" @default.
• W1985732970 modified "2023-10-03" @default.
• W1985732970 title "Convenient asymmetric (salen)Mn(III)-catalyzed epoxidation of unfunctionalized alkenes with hydrogen peroxide using carboxylate salt cocatalysts" @default.
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• W1985732970 doi "https://doi.org/10.1016/s0040-4020(98)00145-8" @default.
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