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- W1985778891 abstract "The Prussian blue analogue, AxM[Fe(CN)6]yzH2O (A and M are an alkali metal and a transition metal, respectively), is one of the candidates for a positive electrode material of a lithium-ion secondary battery. For further development of the electrode material, deeper understanding of the redox states of the constituents, i.e., M and the Fe(CN)6 unit, is indispensable. Here, we investigated the electronic state of the redox constituents of K0.34Co[Fe(CN)6]0.753.6H2O by means of the electrostatic potential method combined with the maximum entropy method combined with the Rietveld analysis (MEM/Rietveld). The electrostatic potential U(r) revealed that both the reduced and oxidixed states of Fe extend to the surrounding CN groups, which may cause the robustness of the cyano-bridged transition metal network." @default.
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- W1985778891 date "2011-02-03" @default.
- W1985778891 modified "2023-09-24" @default.
- W1985778891 title "Extended d-Electron State of Fe(CN)6Unit in Prussian Blue Analogue" @default.
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- W1985778891 doi "https://doi.org/10.1143/apex.4.025801" @default.
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