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• W1985824512 abstract "The removal of thiophene from a hydrocarbon mixture by a novel Cu−Al2O3 adsorbent was investigated under ambient conditions. An adsorbent with 5 wt % Cu showed the highest capacity, 1.8 mg/g (milligram of sulfur per gram of adsorbent). A sol−gel process followed by hypercritical drying, calcination, and thermovacuum treatment was successfully used to prepare the adsorbents. The adsorbents were characterized by Brunauer−Emmett−Teller specific surface area (BET), X-ray diffraction (XRD), and UV−vis diffuse reflectance spectroscopy (UV−vis). The characterization results suggested that copper ion with +1 valence was responsible for the adsorptive performance. Metallic copper (Cu0) and Cu2+ were not effective for the adsorption of thiophene. It seemed that Cu+ coordinated to thiophene through the sulfur atom, which was different from the mechanism of π-complexation proposed in the literature." @default.
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• W1985824512 date "2006-08-01" @default.
• W1985824512 modified "2023-09-26" @default.
• W1985824512 title "Sol−Gel Cu−Al₂O₃ Adsorbents for Selective Adsorption of Thiophene out of Hydrocarbon" @default.
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• W1985824512 doi "https://doi.org/10.1021/ie060559t" @default.
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