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• W1985857639 endingPage "1474" @default.
• W1985857639 startingPage "1469" @default.
• W1985857639 abstract "The new ligand N-(5-methyl-2,2′-bipyridyl)-1,8-naphthalimide has been prepared by the reaction of 1,8-naphthalimide, 5-(bromomethyl)-2,2′-bipyridine and potassium carbonate in refluxing acetone. Reaction of this ligand and bis(bipyridyl)ruthenium(II) dichloride in refluxing ethanol followed by anion exchange with ammonium hexafluorophosphate produces {ruthenium[bis(bipyridyl)][N-(5-methyl-2,2′-bipyridyl)-1,8-naphthalimide]}(PF6)2 (1). In both the solid state (X-ray analysis) and in solution (shown by PGSE-NMR analysis), the 1,8-naphthalimide synthon organizes the cationic metal units into dimers with a strong, directionally oriented (head to tail) π–π stacking interaction. UV–VIS, fluorescence spectroscopy and electrochemical studies indicate that even with the strong interactions of the 1,8-naphthalimide groups, it does not have a significant influence on the properties of the [Ru(bipy)3]2+ core." @default.
• W1985857639 created "2016-06-24" @default.
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• W1985857639 date "2009-06-01" @default.
• W1985857639 modified "2023-09-25" @default.
• W1985857639 title "Structural organization of a {ruthenium[tris(bipyridyl)]}2+ complex by strong π–π stacking of a tethered 1,8-naphthalimide synthon: Impact on electrochemical and spectral properties" @default.
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• W1985857639 doi "https://doi.org/10.1016/j.poly.2009.03.009" @default.
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