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• W1985885560 abstract "First rotaxane having tert-ammonium axle was prepared from tert-ammonium salt axle and dibenzo-24-crown-8-ether (DB24C8) wheel, suggesting that tert-ammonium salt axle forms the corresponding threaded complex with a crown ether. Same rotaxane was obtained quantitatively by N-methylation of sec-ammonium-type rotaxane. The tert-ammonium-type rotaxane was neutralized with amine base to tert-amine-type rotaxane in 100% yield, indicating the first isolation of ‘nonionic’ amine-type rotaxane. The reversible protonation and deprotonation of tert-amine-type rotaxane were achieved." @default.
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• W1985885560 date "2008-04-01" @default.
• W1985885560 modified "2023-10-15" @default.
• W1985885560 title "Crown ether–tert-ammonium salt complex fixed as rotaxane and its derivation to nonionic rotaxane" @default.
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• W1985885560 doi "https://doi.org/10.1016/j.tetlet.2008.02.073" @default.
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