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- W1985890272 abstract "Abstract NH3(MoO3)3 crystallizes with hexagonal symmetry, space group P6 3 m , lattice constants a = 10.568 A, c = 3.726 A, and Z = 2. The crystal structure has been determined by Patterson synthesis and refined assuming isotropic temperature factors to a final conventional R value of 0.085. The structure shows a three-dimensional arrangement built up of double chains of distorted MoO6 octahedra, parallel to the [001] direction. The octahedral double chains are linked among each other through common oxygen atoms. In addition to the shared oxygen atoms, each molybdenum is coordinated to one terminal oxygen. MoO distances range from 1.645 to 2.378 A and OMoO angles from 74.3 to 114.3°. These results are consistent with the fact that molybdenum in high-valence states shows octahedral coordination with terminal oxygens." @default.
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- W1985890272 date "1985-06-01" @default.
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- W1985890272 title "Synthesis and crystal chemistry of NH3(MoO3)3" @default.
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- W1985890272 doi "https://doi.org/10.1016/0022-4596(85)90272-5" @default.
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