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• W1985890882 abstract "Mixed nickel cerium oxides have been used for studying the enantioselective hydrogenation of methyl acetoacetate (MAA) in methyl (3)-hydroxybutyrate (MHB). X-ray photoelectron spectroscopy (XPS) and infrared spectroscopy (FTIR) provide interesting information about the adsorption of both the reagent and the modifying agent (viz: tartaric acid). From the XPS results, we can assume that the presence of Ce3+ species, the amount of which is depending on the Nickel extent, stabilises a complex tartarate salt. The whole information lead to a new model with a stable six-membered cycle, in which the methylenic group of the reagent is involved." @default.
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• W1985890882 date "1998-03-01" @default.
• W1985890882 modified "2023-09-26" @default.
• W1985890882 title "X-ray photoelectron spectroscopy and infrared spectroscopy studies for the mechanism of the enantioselective hydrogenation of methyl acetoacetate over mixed nickel–cerium oxides" @default.
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• W1985890882 doi "https://doi.org/10.1016/s0926-860x(97)00359-1" @default.
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