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- W1985928945 abstract "Abstract Direct aldol reactions of 4-methyl-1-piperidone, tropinone and granatanone (pseudopelletierine) take place spontaneously in the presence of water without any catalyst or additional reagents. The anti / syn -diastereoselectivity of the aqueous aldol reaction depends on the amount of water used. The syn -selectivity of the reaction is probably due to the thermodynamic control. Excellent atom economy and low E factors together with anti -selectivity as high as 98:2 for the tropinone aldol were obtained." @default.
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- W1985928945 date "2011-10-01" @default.
- W1985928945 modified "2023-09-24" @default.
- W1985928945 title "Spontaneous and diastereoselective aldol reactions of cyclic β-amino ketones in the presence of water" @default.
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- W1985928945 doi "https://doi.org/10.1016/j.tetlet.2011.08.107" @default.
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