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- W1985954722 abstract "The syntheses of several fully protected dipeptide isosteres which incorporate a methylene-oxy bond replacing the amide bond are described. The novel methylene-oxy modification offers a polar, flexible, proteolytically resistant peptide bond surrogate which can be easily incorporated into biologically active peptides. The standard geometries of the trans-amide, methylene-oxy and methylene-thio units are compared, showing a very close geometrical resemblance of the ψ[CH2-0] unit to the amide bond." @default.
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- W1985954722 date "1986-01-01" @default.
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- W1985954722 title "Synthesis of isosteric methylene-oxy pseudodipeptide analogues as novel amide bond surrogate units" @default.
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- W1985954722 doi "https://doi.org/10.1016/s0040-4020(01)96090-9" @default.
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