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- W1986001569 abstract "During the oxidation of conjugated enones to α-acyloxyoxiranes by m-chloroperbenzoic acid, the preferred sequence is epoxidation followed by Baeyer-Villiger oxidation. Rearrangement of acyloxyoxiranes to α-acyloxyketones, in situ, was observed. The α-ketoacetate structure assigned previously to the m-CPBA oxidation product of 5α-androst-16-ene-3α,17-diol 3-benzoate 17-acetate, has been revised to an acyloxyoxirane structure based on spectroscopic and X-ray diffraction data." @default.
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- W1986001569 date "1992-01-01" @default.
- W1986001569 modified "2023-10-18" @default.
- W1986001569 title "Rearrangement of acyloxyoxiranes: A revised structure for the oxidation product of 5α-androst-16-ene-3α, 17-diol 3-benzoate 17-acetate" @default.
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- W1986001569 doi "https://doi.org/10.1016/s0040-4020(01)89038-4" @default.
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