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• W1986014933 abstract "Recently, we developed a “crystalline” plastic optical fiber with excellent heat resistance and dimensional stability. For the practical use of this crystalline optical fiber in the near future, an accurate control of the solid-state structure is indispensable because of the necessity of reducing light refraction at the crystalline/amorphous interface. In the present study, changes in the fine structure and lamella arrangement upon drawing poly[tetrafluoroethylene-co-(perfluoroethylvinylether)] (abbrev. EFA) transparent crystalline fibers were investigated by using wide-angle X-ray diffraction (WAXD) and small-angle X-ray scattering (SAXS) methods. The EFA was crystallized as a lamella crystal in the fibers and formed a thicker lamella (thickness: at least 27 nm). This polymer might form a “switchboard-type” lamella. Upon the drawing of the EFA fibers, four-point SAXS diagrams developed in the photograph, which implied that a particular type of layer structure, an alternately tilted lamella arrangement known as the herringbone, was formed. Moreover, the previously proposed packing mode of general fluorinated polymers was required to be modified from quasi-hexagonal to orthorhombic in a reciprocal lattice in order to assign all reflective indexes." @default.
• W1986014933 created "2016-06-24" @default.
• W1986014933 creator A5058432569 @default.
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• W1986014933 date "2008-09-24" @default.
• W1986014933 modified "2023-10-17" @default.
• W1986014933 title "Changes in Arrangement of Lamella and Fine Crystallite in Fluorinated “Crystalline” Transparent Fibers with Drawing" @default.
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• W1986014933 doi "https://doi.org/10.1021/ma800801d" @default.
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