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- W1986016321 abstract "We studied shear-induced fracture and self-healing of well-defined transient polymer networks formed by telechelic polypeptides, with nodes formed by collagen-like triple helices. When these gels are sheared at a rate that is higher than the inverse relaxation time of the nodes, fracture occurs at a critical stress which increases logarithmically with increasing shear rate. When a constant stress is applied, fracture occurs after a delay time that decreases exponentially with increasing stress. These observations indicate that fracture in these systems is due to stress-activated rupture of triple-helical junctions. After rupture, the physical gels heal completely." @default.
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- W1986016321 date "2010-03-11" @default.
- W1986016321 modified "2023-10-14" @default.
- W1986016321 title "Fracture and Self-Healing in a Well-Defined Self-Assembled Polymer Network" @default.
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- W1986016321 doi "https://doi.org/10.1021/ma1000173" @default.
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