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- W1986019671 abstract "A facile ring-opening reaction has been observed for 5,7,12,14-tetra hydrodibenzo[c,h][1,6]dithiecin (5) and 1,4,8,11-tetramethyl-5,7,12,14-tetrahydrodibenzo[c,h][1,6]dithiecin (6) on treatment with pyridinium hydrobromide perbromide. Compound (5) gave mainly bis(o-bromomethylbenzyl) disulphide (9) together with trace amounts of 1,2-bis(bromomethyl)benzene and 1,4-dihydro-2,3-benzodithiin (8). Similar products were isolated for compound (6). A reaction pathway involving the participation of the two transannular sulphur atoms in these systems is proposed." @default.
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- W1986019671 date "1979-01-01" @default.
- W1986019671 modified "2023-09-26" @default.
- W1986019671 title "Transannular brominolysis of 5,7,12,14-tetrahydrodibenzo [c,h][1,6] dithiecins by pyridinium hydrobromide perbromide" @default.
- W1986019671 doi "https://doi.org/10.1039/p19790001475" @default.
- W1986019671 hasPublicationYear "1979" @default.
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