FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1986032356> ?p ?o ?g. }

• W1986032356 endingPage "13106" @default.
• W1986032356 startingPage "13101" @default.
• W1986032356 abstract "The solution structure of a synthetic DNA mini-hairpin possessing a stilbenediether linker and three G:C base pairs has been obtained using (1)H NMR spectral data and constrained torsion angle molecular dynamics. Notable features of this structure include a compact hairpin loop having a short stilbene-guanine plane-to-plane distance and approximate B-DNA geometry for the three base pairs. Comparison of the electronic spectra of mini-hairpins having one-to-four G:C base pairs and stilbenediether or hexamethyleneglycol linkers reveals the presence of features in the UV and CD spectra of the stilbene-linked hairpins that are not observed for the ethyleneglycol-linked hairpins. Investigation of the electronic structure of a stilbene-linked hairpin having a single G:C base pair by means of time-dependent density functional theory shows that the highest occupied molecular orbital, but not the lowest unoccupied molecular orbital, is delocalized over the stilbene and adjacent guanine. The calculated UV and CD spectra are highly dependent upon hairpin conformation, but reproduce the major features of the experimental spectra. These results illustrate the utility of an integrated experimental and theoretical approach to understanding the complex electronic spectra of pi-stacked chromophores." @default.
• W1986032356 created "2016-06-24" @default.
• W1986032356 creator A5010065037 @default.
• W1986032356 creator A5012159933 @default.
• W1986032356 creator A5064735594 @default.
• W1986032356 creator A5069380959 @default.
• W1986032356 creator A5085196462 @default.
• W1986032356 date "2007-10-25" @default.
• W1986032356 modified "2023-09-23" @default.
• W1986032356 title "Structure and Electronic Spectra of DNA Mini-hairpins with G<i>_n</i>:C<i>_n</i> Stems" @default.
• W1986032356 cites W1965655451 @default.
• W1986032356 cites W1966027684 @default.
• W1986032356 cites W2005334176 @default.
• W1986032356 cites W2015239003 @default.
• W1986032356 cites W2021786084 @default.
• W1986032356 cites W2050595677 @default.
• W1986032356 cites W2055467986 @default.
• W1986032356 cites W2056669656 @default.
• W1986032356 cites W2075945883 @default.
• W1986032356 cites W2086575452 @default.
• W1986032356 cites W2135848727 @default.
• W1986032356 cites W2140635800 @default.
• W1986032356 cites W2150345533 @default.
• W1986032356 cites W280694366 @default.
• W1986032356 doi "https://doi.org/10.1021/jp072303m" @default.
• W1986032356 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17958411" @default.
• W1986032356 hasPublicationYear "2007" @default.
• W1986032356 type Work @default.
• W1986032356 sameAs 1986032356 @default.
• W1986032356 citedByCount "15" @default.
• W1986032356 countsByYear W19860323562012 @default.
• W1986032356 countsByYear W19860323562013 @default.
• W1986032356 countsByYear W19860323562014 @default.
• W1986032356 countsByYear W19860323562015 @default.
• W1986032356 countsByYear W19860323562017 @default.
• W1986032356 countsByYear W19860323562022 @default.
• W1986032356 crossrefType "journal-article" @default.
• W1986032356 hasAuthorship W1986032356A5010065037 @default.
• W1986032356 hasAuthorship W1986032356A5012159933 @default.
• W1986032356 hasAuthorship W1986032356A5064735594 @default.
• W1986032356 hasAuthorship W1986032356A5069380959 @default.
• W1986032356 hasAuthorship W1986032356A5085196462 @default.
• W1986032356 hasBestOaLocation W19860323562 @default.
• W1986032356 hasConcept C104317684 @default.
• W1986032356 hasConcept C112887158 @default.
• W1986032356 hasConcept C121332964 @default.
• W1986032356 hasConcept C1276947 @default.
• W1986032356 hasConcept C134306372 @default.
• W1986032356 hasConcept C139358910 @default.
• W1986032356 hasConcept C147597530 @default.
• W1986032356 hasConcept C152365726 @default.
• W1986032356 hasConcept C178790620 @default.
• W1986032356 hasConcept C185581394 @default.
• W1986032356 hasConcept C185592680 @default.
• W1986032356 hasConcept C192468462 @default.
• W1986032356 hasConcept C2778301229 @default.
• W1986032356 hasConcept C32909587 @default.
• W1986032356 hasConcept C33923547 @default.
• W1986032356 hasConcept C41999313 @default.
• W1986032356 hasConcept C42058472 @default.
• W1986032356 hasConcept C4839761 @default.
• W1986032356 hasConcept C512185932 @default.
• W1986032356 hasConcept C552990157 @default.
• W1986032356 hasConcept C55493867 @default.
• W1986032356 hasConcept C70050531 @default.
• W1986032356 hasConcept C75473681 @default.
• W1986032356 hasConcept C8010536 @default.
• W1986032356 hasConcept C86025842 @default.
• W1986032356 hasConcept C89025888 @default.
• W1986032356 hasConceptScore W1986032356C104317684 @default.
• W1986032356 hasConceptScore W1986032356C112887158 @default.
• W1986032356 hasConceptScore W1986032356C121332964 @default.
• W1986032356 hasConceptScore W1986032356C1276947 @default.
• W1986032356 hasConceptScore W1986032356C134306372 @default.
• W1986032356 hasConceptScore W1986032356C139358910 @default.
• W1986032356 hasConceptScore W1986032356C147597530 @default.
• W1986032356 hasConceptScore W1986032356C152365726 @default.
• W1986032356 hasConceptScore W1986032356C178790620 @default.
• W1986032356 hasConceptScore W1986032356C185581394 @default.
• W1986032356 hasConceptScore W1986032356C185592680 @default.
• W1986032356 hasConceptScore W1986032356C192468462 @default.
• W1986032356 hasConceptScore W1986032356C2778301229 @default.
• W1986032356 hasConceptScore W1986032356C32909587 @default.
• W1986032356 hasConceptScore W1986032356C33923547 @default.
• W1986032356 hasConceptScore W1986032356C41999313 @default.
• W1986032356 hasConceptScore W1986032356C42058472 @default.
• W1986032356 hasConceptScore W1986032356C4839761 @default.
• W1986032356 hasConceptScore W1986032356C512185932 @default.
• W1986032356 hasConceptScore W1986032356C552990157 @default.
• W1986032356 hasConceptScore W1986032356C55493867 @default.
• W1986032356 hasConceptScore W1986032356C70050531 @default.
• W1986032356 hasConceptScore W1986032356C75473681 @default.
• W1986032356 hasConceptScore W1986032356C8010536 @default.
• W1986032356 hasConceptScore W1986032356C86025842 @default.
• W1986032356 hasConceptScore W1986032356C89025888 @default.
• W1986032356 hasIssue "45" @default.
• W1986032356 hasLocation W19860323561 @default.
• W1986032356 hasLocation W19860323562 @default.

• next