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- W1986061452 abstract "Abstract A new kind of secondarily formed peaks was found in cyclic and stripping voltammetry in neutral sulphate, perchlorate and nitrate supporting electrolytes containing some divalent cations and a substance (for example O 2 ), the reduction of which gives as a by-product OH − ions. The hydroxides deposited in the vicinity of the mercury electrode, in the course of a cathodic scan, react during the anodic scan according to the reaction Hg+Me(OH) 2 =Hg(OH) 2 +Me 2+ +2 e forming a new, separate anodic peak. It was found that silver exerts a catalytic effect on the reduction of NO 3 − ions on the mercury electrode. In neutral nitrate supporting electrolyte containing Ag + ions the hydroxides of some cations (Cd 2+ , Zn 2+ , Mn 2+ , Co 2+ and Ni 2+ ) were deposited during the cathodic scan or during the preelectrolysis. Afterwards, in the course of the anodic scan, a new peak, of the kind described above, was observed. The same effect was formerly interpreted, for Zn 2+ and Cd 2+ , as evidence for the formation of intermetallic compounds, AgZn and AgCd." @default.
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- W1986061452 date "1976-03-01" @default.
- W1986061452 modified "2023-09-26" @default.
- W1986061452 title "Interfering influence of silver on the voltammetric behaviour of Cd2+ and Zn2+ ions on hmde in supporting electrolytes containing nitrates" @default.
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- W1986061452 doi "https://doi.org/10.1016/s0022-0728(76)80007-1" @default.
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