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- W1986098981 abstract "The Ugi four-component condensation between cycloalkanones, isocyanides, and ammonium formate affords N-substituted 1-formylamino-1-cycloalkanecarboxamides 1 which are dehydrated to give the corresponding isocyanides 2. Compounds 2 are cyclized with arylsulfenyl thiocyanates to 1,3-diazaspiro-2-thiones 4 and 5. A series of 1,3-diazaspiro[4,5]dec-1-en-4-ones 7 is prepared by cyclizing 2c–j with butyllithium. The structures of these compounds are confirmed by means of IR, 1H-NMR, and X-ray analysis." @default.
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- W1986098981 date "1991-09-12" @default.
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- W1986098981 title "Studies on isocyanides and related compounds. – Synthesis and cyclization ofN-substituted 1-isocyano-1-cycloalkanecarboxamides" @default.
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- W1986098981 doi "https://doi.org/10.1002/jlac.1991199101145" @default.
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