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• W1986130263 abstract "The Raman non-coincidence effect of the symmetric C=O stretching band was measured in liquid acetone and N,N-dimethylformamide confined to porous silica glasses prepared by the sol—gel process. The experiments were carried out both on bulk liquids and liquids confined to glasses with pore radii from 17—76 Å at 293 K. The value of the non-coincidence was decreased with decreasing pore radius (R) and scaled approximately as 1/R. Additional information about the role of pore surface effects was obtained by measurements on the polar liquids confined to surface-modified glasses when the surface hydroxyl groups were replaced by OSi(CH3)3 groups. The experimental data show that the non-coincidence effect is independent of the pore size in surface-modified glasses." @default.
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• W1986130263 date "1995-11-01" @default.
• W1986130263 modified "2023-10-18" @default.
• W1986130263 title "Raman non-coincidence effect of the carbonyl stretching mode in confined polar liquids" @default.
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• W1986130263 doi "https://doi.org/10.1002/jrs.1250261107" @default.
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