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- W1986175557 abstract "The low frequency infrared spectra from 450 to 75 cm −1 of seven oximes and five aldoximes have been recorded for pure samples and for dilute solutions in cyclohexane. An intense characteristic band is present in the solution spectra at 367 ± 10 cm −1 . This characteristic band shifts to 275 ± 10 cm −1 in the spectra of the OD compounds. The 367 ± 10 cm −1 and 275 ± 10 cm −1 bands are assigned to OH and OD torsional vibrations. A comparison of the solution spectra with spectra of the solid samples indicated that the OH … N hydrogen bond stretch of oximes and aldoximes occurs in 300 to 200 cm −1 region. Strong bands also are present in 140 to 100 cm −1 region which are due to OH … N bending modes or perhaps lattice vibrations." @default.
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- W1986175557 date "1973-01-01" @default.
- W1986175557 modified "2023-09-23" @default.
- W1986175557 title "Far Infrared Group Frequencies. V. Oximes and Aldoximes" @default.
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- W1986175557 doi "https://doi.org/10.1366/000370273774333939" @default.
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