Matches in SemOpenAlex for { <https://semopenalex.org/work/W1986179833> ?p ?o ?g. }
- W1986179833 endingPage "56" @default.
- W1986179833 startingPage "49" @default.
- W1986179833 abstract "The kinetics of heterogeneous electron transfer across films of electronically conducting nickel-4,4′,4″,4‴-tetraaminophthalocyanine polymer (poly(NiTAPc)) are reported. Poly(NiTAPc), which is formed by oxidative electropolymerization of NiTAPc, acts as an n-doped electronic conductor between about 0.8 and −2.0 V vs. Ag/AgCl. Within this range it sustains diffusion-limited charge transfer to one-electron bulk solution reactants at their anticipated formal potentials. However, the rates of heterogeneous electron transfer to these species are diminished by a small, uniform amount that is exponentially dependent on film thickness. Results are interpreted in terms of a porous electrode model in which electron transfer occurs at the polymer—solution interface, a large bulk capacitance arises from an interior pore volume that is inaccessible to diffusing reactants and a resistive element (suggested to be pores of electrolyte trapped between aggregrates of the polymer) is present which acts to reduce apparent values of ks,h. It is demonstrated that electronically conducting polymer films do not accelerate the rate of electron transfer to solution reactants but rather restore kinetics to their anticipated values by preventing suface involvement." @default.
- W1986179833 created "2016-06-24" @default.
- W1986179833 creator A5017462609 @default.
- W1986179833 creator A5027307836 @default.
- W1986179833 date "1993-12-01" @default.
- W1986179833 modified "2023-09-26" @default.
- W1986179833 title "Heterogeneous electron transfer at electrodes coated with electronically conducting nickel-tetraaminophthalocyanine polymer films" @default.
- W1986179833 cites W1940945561 @default.
- W1986179833 cites W1965863895 @default.
- W1986179833 cites W1976255248 @default.
- W1986179833 cites W1978606215 @default.
- W1986179833 cites W1985093064 @default.
- W1986179833 cites W1992562656 @default.
- W1986179833 cites W1993869848 @default.
- W1986179833 cites W2002987606 @default.
- W1986179833 cites W2003024671 @default.
- W1986179833 cites W2004515385 @default.
- W1986179833 cites W2006052134 @default.
- W1986179833 cites W2006990188 @default.
- W1986179833 cites W2007823215 @default.
- W1986179833 cites W2008261043 @default.
- W1986179833 cites W2015013961 @default.
- W1986179833 cites W2023613494 @default.
- W1986179833 cites W2027327489 @default.
- W1986179833 cites W2031088057 @default.
- W1986179833 cites W2036987344 @default.
- W1986179833 cites W2037768942 @default.
- W1986179833 cites W2038259247 @default.
- W1986179833 cites W2040496087 @default.
- W1986179833 cites W2041474993 @default.
- W1986179833 cites W2047409333 @default.
- W1986179833 cites W2047665323 @default.
- W1986179833 cites W2048290984 @default.
- W1986179833 cites W2056690088 @default.
- W1986179833 cites W2057624519 @default.
- W1986179833 cites W2061624370 @default.
- W1986179833 cites W2068046806 @default.
- W1986179833 cites W2072749499 @default.
- W1986179833 cites W2076060780 @default.
- W1986179833 cites W2076593084 @default.
- W1986179833 cites W2076987538 @default.
- W1986179833 cites W2080870150 @default.
- W1986179833 cites W2082315634 @default.
- W1986179833 cites W2089462088 @default.
- W1986179833 cites W2089488208 @default.
- W1986179833 cites W2089956653 @default.
- W1986179833 cites W2091704219 @default.
- W1986179833 cites W2093667762 @default.
- W1986179833 cites W2093989983 @default.
- W1986179833 cites W2103543334 @default.
- W1986179833 cites W2158553650 @default.
- W1986179833 cites W2951177149 @default.
- W1986179833 cites W2952419103 @default.
- W1986179833 doi "https://doi.org/10.1016/0022-0728(93)87037-v" @default.
- W1986179833 hasPublicationYear "1993" @default.
- W1986179833 type Work @default.
- W1986179833 sameAs 1986179833 @default.
- W1986179833 citedByCount "10" @default.
- W1986179833 countsByYear W19861798332013 @default.
- W1986179833 countsByYear W19861798332018 @default.
- W1986179833 crossrefType "journal-article" @default.
- W1986179833 hasAuthorship W1986179833A5017462609 @default.
- W1986179833 hasAuthorship W1986179833A5027307836 @default.
- W1986179833 hasConcept C113196181 @default.
- W1986179833 hasConcept C121332964 @default.
- W1986179833 hasConcept C123669783 @default.
- W1986179833 hasConcept C127413603 @default.
- W1986179833 hasConcept C133495861 @default.
- W1986179833 hasConcept C147120987 @default.
- W1986179833 hasConcept C147789679 @default.
- W1986179833 hasConcept C148898269 @default.
- W1986179833 hasConcept C159467904 @default.
- W1986179833 hasConcept C17525397 @default.
- W1986179833 hasConcept C178790620 @default.
- W1986179833 hasConcept C185592680 @default.
- W1986179833 hasConcept C188027245 @default.
- W1986179833 hasConcept C42360764 @default.
- W1986179833 hasConcept C504270822 @default.
- W1986179833 hasConcept C521977710 @default.
- W1986179833 hasConcept C52859227 @default.
- W1986179833 hasConcept C62520636 @default.
- W1986179833 hasConcept C68801617 @default.
- W1986179833 hasConcept C69357855 @default.
- W1986179833 hasConcept C97355855 @default.
- W1986179833 hasConceptScore W1986179833C113196181 @default.
- W1986179833 hasConceptScore W1986179833C121332964 @default.
- W1986179833 hasConceptScore W1986179833C123669783 @default.
- W1986179833 hasConceptScore W1986179833C127413603 @default.
- W1986179833 hasConceptScore W1986179833C133495861 @default.
- W1986179833 hasConceptScore W1986179833C147120987 @default.
- W1986179833 hasConceptScore W1986179833C147789679 @default.
- W1986179833 hasConceptScore W1986179833C148898269 @default.
- W1986179833 hasConceptScore W1986179833C159467904 @default.
- W1986179833 hasConceptScore W1986179833C17525397 @default.
- W1986179833 hasConceptScore W1986179833C178790620 @default.
- W1986179833 hasConceptScore W1986179833C185592680 @default.
- W1986179833 hasConceptScore W1986179833C188027245 @default.
- W1986179833 hasConceptScore W1986179833C42360764 @default.