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- W1986229785 abstract "l-Gulose, an essential component for the antibiotic and antitumor activities of bleomycin A2, was synthesized in 47% yield from d-glucono-1,5-lactone. The effective cleavage of acetonides by SnCl2 in the presence of tert-butyldimethylsilyl ethers was of importance in the course of synthesis. Elaboration of d-glucono-1,5-lactone that includes a step of oxidative degradation by Dess–Martin periodinane also afforded a respectable yield of l-xylose." @default.
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- W1986229785 date "2002-01-01" @default.
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- W1986229785 title "The synthesis of l-gulose and l-xylose from d-gluconolactone" @default.
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- W1986229785 doi "https://doi.org/10.1016/s0040-4020(01)01146-2" @default.
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