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- W1986240655 abstract "The energy transfer reaction Xe(3P0,2) + N2(X) → Xe(1S0) + N2(B 3Πg) is analyzed by extensive numerical calculations of the dynamics. The potential energy surfaces used were previously shown to account qualitatively for the experimental findings. The present calculations are aimed at an explanation of the branching ratios between the vibrational levels of the N2(B) product as previously measured at several collision energies. The collisions are treated as sudden with respect to molecular rotation and the reaction is assumed to be adiabatic on vibronic states. Those crossings between entrance and exit channels which are responsible for the nonadiabatic transitions are identified by symmetry analysis and numerical experiments, using the Landau-Zener theory. Information on the strength and radial dependence of the relevant coupling matrix element is obtained. The separability between vibrational and electronic degrees of freedom is discussed. In certain cases the nonadiabatic transitions are so fast that molecular rearrangement can be neglected (sudden behaviour), while in other cases they are slower than vibrations (adiabatic behaviour). In the sudden limit the Franck-Condon factors between the N2(X) and N2(B) vibrational wavefunctions have to be taken into account, but in the adiabatic limit they are unimportant." @default.
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- W1986240655 date "1994-09-01" @default.
- W1986240655 modified "2023-10-16" @default.
- W1986240655 title "On the dynamics of the vibrationally selective electronic energy transfer from metastable xenon atoms to nitrogen molecules" @default.
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- W1986240655 doi "https://doi.org/10.1016/0301-0104(94)00168-5" @default.
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