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- W1986242583 abstract "Abstract Numerical calculations of the non-equilibrium laminar boundary-layer flow of dissociating air are conducted. The finite-rate chemistry model adopted for use in the analysis is elaborate, considering 22 elementary reactions between 9 chemical species (N 2 , O 2 , N, O, NO, NO 2 , N 2 O, NO 3 and O 3 ). An effective explicit finite-difference procedure, based on a scheme originally proposed by Du Fort and Frankel, is formulated for solving the governing partial differential equations with Soret and Dufour effects included in the boundary layer. At the wall, the limiting cases of a non-catalytic and a fully catalytic wall are considered. Predictions of velocity, temperature and mass fractions of chemical species are obtained. The numerical results demonstrate the importance of considering the non-equilibrium aspects of the flow rather than the limiting cases of either frozen or equilibrium flow. The mass fractions of chemical species are strongly influenced by the catalycity of the wall, whereas the catalytic recombination at the wall surface has no significant influence on the velocity and temperature profiles. Calculated effective speeds of the elementary processes show the importance of the individual reactions and the role of the NO 2 - and N 2 O-reactions in the production of nitric oxide." @default.
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- W1986242583 date "1976-05-01" @default.
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- W1986242583 title "Non-equilibrium laminar boundary-layer flow of dissociating air" @default.
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- W1986242583 doi "https://doi.org/10.1016/0094-5765(76)90144-2" @default.
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