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- W1986243971 abstract "Abstract Some new complexes of antimony (III) of the type Sb(O2Ph) (A)2Cl have been obtained by reacting antimony trichloride with acid amides (formamide, dimethylformamide and urea) and phenols (catechol and pyrogallol). Two molecules of the amides coordinate to the antimony atom through oxygen while only one molecule of DMSO coordinates to the antimony atom through an oxygen atom to give complexes of the type Sb(O2Ph) (DMSO)Cl; the phenols act as diacid chelating ligands. These complexes react with sodium cyclopentadienide to give cyclopentadienyl derivatives of the type Sb(O2Ph) (A)2Cp and Sb(O2Ph) (DMSO)Cp, respectively. The complexes are characterized by their elemental analysis, IR and electronic spectra, and other characteristics. It is suggested that the cyclopentadienyl ring is σ bonded to antimony in the amide complexes whereas this bond has some π -character in the DMSO complexes. (Ph is the phenolic residue, A is the amide molecule, DMSO is dimethylsulphoxide, and Cp is the cyclopentadienyl group)." @default.
- W1986243971 created "2016-06-24" @default.
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- W1986243971 date "1984-01-01" @default.
- W1986243971 modified "2023-09-25" @default.
- W1986243971 title "Synthesis of Some Mixed Coordination Complexes of Antimony Trichloride with Phenols, Acid Amides, Dimethyl Sulphoxide and Cyclopentadiene" @default.
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- W1986243971 doi "https://doi.org/10.1080/00945718408068777" @default.
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