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- W1986271504 abstract "X-ray diffraction and diffuse reflection IR spectroscopic measurements have been carried out on amorphous NaCl–glucose mixtures, a-(NaCl)x(glucose)1−x, with x = 0, 0.05, 0.1 and 0.15, in order to obtain structural information on the intermolecular hydrogen-bonded interaction between glucose molecules affected by the presence of NaCl. The difference distribution function Δginter(r) was derived from the Fourier transform of the difference intermolecular interference term Δiinter(Q) between X-ray intermolecular interference terms observed from amorphous NaCl-glucose and pure glucose samples. A negative peak appears at r ≈ 2.5 Å in the Δginter(r) observed for the 10 mol% NaCl sample, while, the Δginter(r) for the 15 mol% NaCl sample does not show pronounced negative peak. On the other hand, the IR spectra for the O–H stretching region (2300 ⩽ ν ⩽ 3800 cm−1) indicate that hydrogen bonds between glucose molecules are significantly collapsed in the samples containing 5–15 mol% NaCl. These results imply that the contribution from the Na+⋯Cl− contact ion pair is dominated in the 15 mol% NaCl sample." @default.
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- W1986271504 date "2007-06-01" @default.
- W1986271504 modified "2023-09-27" @default.
- W1986271504 title "Structure of amorphous NaCl–glucose system studied by X-ray diffraction and IR methods" @default.
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- W1986271504 doi "https://doi.org/10.1016/j.jnoncrysol.2007.02.025" @default.
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